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TGW5: Nitric acid and calcium carbonate
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Notes on the ‘Think for yourself’ questions
What tells you there is a chemical reaction?
The calcium carbonate is ‘used up’. A new substance that is in the gas state is formed. It does not dissolve in water and bubbles out.
Think of the substances that you know to be in the gas state at room temperature. Which four could be made using the atoms that are in the formulae of nitric acid and calcium carbonate?
Hydrogen, oxygen, ammonia and carbon dioxide.
Which one of these four substances is very soluble in water and would dissolve rather than bubble out?
Ammonia. (Carbon dioxide is slightly soluble in water at room temperature. Some would dissolve, but the solution would soon be saturated and the rest would bubble out).
When tested, the gas turns limewater milky. Which substance is it?
Carbon dioxide.
Must there be other new substances in solution? Look at the formulae and account for the atoms.
Yes: calcium, nitrogen and hydrogen atoms are still unaccounted for. Also, each carbon atom only uses two oxygen atoms to make carbon dioxide, so there are some oxygen atoms not accounted for yet.
How would you know when you had added enough calcium carbonate to react with all of the nitric acid?
There would be some left over calcium carbonate which would be visible ( because it does not dissolve).
How could you separate out the left over calcium carbonate?
Filter the mixture: a clear colourless, solution should drip through the filter paper.
How could you separate out any new substance that was dissolved?
Leave it for the water to evaporate. (Some substances might evaporate with the water, but it would be worth a
try).

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tgw1: acid
tgw2: notes
tgw3: questions
tgw4: notes
tgw5: notes
tgw6: nitric acid
tgw7: notes

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